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  1. Good article Christine,

    When I placed a verbal submission to the Zero Carbon roadshow panel two weeks ago I spoke about the widespread emmissions of tyre particulates as they are made from plastic ingredients also and are cancer causing annd are now found on the icecaps carried accooss the oceans also to cause the ice caps to melt due to the black carbon attracting heat from the sun.

    The climate change panel was astounded at this and confessed they had not considered that synthetic tyres were even a hazard!!!!

    Any chemical engineer will know that synthetic tyres are made from a solutiion of all types of ingredients that contain plastics, so we need now to add tyre use to the list of toxic chemicals that are destroying our environment. -Synthetic rubber (SBR – styreneised polyisobutylene)

    http://rcaforum.org.nz/sites/public_files/documents/stormwateremissionfactors.pdf

    Based upon the available data, Table 4.14 provides a summary of median or selected concentration data for key organic compounds in tyres.

    To provide more suitable data to assess emissions of organic contaminants from this source additional information and refinement of data is required as identified above in Section 4.4.2 and below in Section 4.4.4. Table 4.14 – Summary of concentrations of selected organic compounds in tyres for use in calculating emission loads (all concentrations mg/kg). Compound Median tyre concentration COPC Benzothiazole 44.7* Pyrene 42.6* Polycyclic aromatic hydrocarbons 226.1** Chlorinated organics 5.3** Others n-Alkanes 18842** n-Alkanoic acids 12197** n-Alkenoic acids 1279** Substituted benzaldehydes 7.8** Benzoic acids 74.8** Polycyclic aromatic ketones and quinones 0.45** Pentacyclic triterpanes 684** Benzaldehydes 19.04** Natural resins 9513** Regular steranes 74.2** Amide (4-phenylbenzamine) 12.9** Note: * From Gadd & Kennedy (2000); ** from Rogge et al. (1993).

    The composition of tyres is dominated by organic compounds, with a wide variety of compounds used in the manufacture of tyres.
    Table 4.6: – General composition of tyres. Main element Use Example compounds Content Polymer base Structure Natural rubber (polyisoprene) Synthetic rubber (SBR – styreneised polyisobutylene) 30% (ratio between 60:40 and 70:30 synthetic: natural rubber) Carbon black Reinforcement, provides stiffness, strength and hardness. Carbon black of various particle sizes 30 Hydrocarbon oil Processing aid/softening agent Paraffinic, naphthenic or aromatic oil 10-15 Resins Processing aids Aromatic hydrocarbon polymer Thermoplastic phenol-novolac resin 0 – 7% Antidegradants Anitoxidants and antiozonants Paraffin wax Quinolines Phenyldiamines 1 – 1.5% Cure activators Assist in curing Zinc oxide/stearic acid mix 2.0 – 2.5% Cure agent Assist in curing Elemental sulphur 1.0 – 1.5% Accelerators Promote curing Complex amines Sulphonamides Thiazoles 1.5% Retarders Slow the curing rate Acids or phthalates 0.1% Bonding agent Improve bond strength between tyre and steel/cord belt Resorcinol resin Bracing Steel (sometimes coated in brass)
    There have been a number of studies investigating the inorganic composition of vehicle tyres, including a major study by Environment Agency in the UK (Environment Agency 1998). This study reports the presence of major elements such as calcium (calcium oxide used as a desiccant), magnesium (magnesium oxide used as an accelerant), silica and phosphates (used in fillers and plasticisers).

  2. I find that in the local supermarket, the packing assistants put meat in one bag, fruit in another & use yet another for e.g., bread & etc.. I usually say put everything into one bag (I buy for myself only).

    As the plastic bags mount up, I take them to the local op shop & the volunteers always welcome them. So much is packaged in plastic, IMO, the 1st packagers should pay for its disposal, Most often, the end purchaser gets lumbered with every cost.

  3. Manufacturing needs to also pay for the cleanup of the vast plastic ocean that is increasing. It is not just plastics its also fabric, almost even worse is fleece fibers, so folks only buy wool. Every time you wash a fleece item it releases millions of unbiodegradable micro fibres into the environment, the waterways and then eventually back into you.

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